| Common Name: | SL SMOKE FLUID |
| Manufacturer: | SUPERIOR SIGNAL |
| SDS Revision Date: | 10/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 59PV48, 59PV49, 59PV50, 59PV51 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SUPERIOR(R*) SL SMOKE FLUID
SAFETY DATA SHEET
REVISION DATE: 10/29/2015
REPLACES ALL PREVIOUS EDITIONS
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: SUPERIOR(R*) SL SMOKE FLUID
1.2 RECOMMENDED USE:
SMOKE GENERATING FLUID EXCLUSIVELY FOR USE IN APPROVED PROFESSIONAL
SMOKE GENERATING EQUIPMENT, FOR SEWER SMOKE TESTING AND OTHER APPROVED
PROFESSIONAL AIR FLOW MARKING APPLICATIONS. FOR PROFESSIONAL USE ONLY.
USE ONLY AS DIRECTED.
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER:
SUPERIOR SIGNAL COMPANY LLC
P.O. BOX 96,
SPOTSWOOD, NJ,
USA
PHONE: 732-251-0800
FAX: 732-251-9442
EMAIL: INFO@SUPERIORSIGNAL.COM
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE: 732-251-0800
| SECTION 2. HAZARDS IDENTIFICATION | |
2.1 GLOBALLY HARMONIZED SYSTEM (GHS) HAZARD CLASSIFICATION:
OSHA CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS): HAZARDOUS.
THIS SDS MEETS THE REQUIREMENTS OF GHS REVISION 3, HCS 2012
(29 CFR 1910.1200).
GHS CLASSIFICATIONS: ASPIRATION HAZARD, CATEGORY 1.
2.2 GHS LABEL ELEMENTS INCLUDING PRECAUTIONARY STATEMENTS:
HAZARD PICTOGRAMS: HEALTH HAZARD
GHS SIGNAL WORD: DANGER
HAZARD STATEMENT: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE GAS/MIST/VAPORS/SPRAY. WEAR PROTECTIVE GLOVES, EYE
OR FACE PROTECTION. AVOID RELEASE TO THE ENVIRONMENT. WHEN USED AS
DIRECTED, PRODUCT DOES NOT POSE HAZARD.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. DO NOT
INDUCE VOMITING.
IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING.
IF SKIN IRRITATION OCCURS, GET MEDICAL ATTENTION.
STORAGE:
STORE IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATION. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROPRIATE TREATMENT AND DISPOSAL
FACILITY IN ACCORDANCE WITH APPLICABLE LAWS AND REGULATIONS, AND PRODUCT
CHARACTERISTICS AT TIME OF DISPOSAL. SEE SECTION 13 OF THIS SDS FOR
DISPOSAL INSTRUCTIONS.
2.3 OTHER HAZARDS WHICH ARE NOT INCLUDED IN THE CLASSIFICATION CRITERIA:
VAPOR CONCENTRATIONS ABOVE RECOMMENDED EXPOSURE LEVELS ARE IRRITATING TO
THE EYES AND THE RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS, ARE
ANESTHETIC, AND MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS. PROLONGED
OR REPEATED SKIN CONTACT WITHOUT PROPER CLEANING CAN CLOG THE PORES OF THE
SKIN RESULTING IN DISORDERS SUCH AS OIL ACNE/FOLLICULITIS.
PROLONGED/REPEATED CONTACT MAY CAUSE DEFATING OF THE SKIN WHICH CAN LEAD
TO DERMATITIS. USED OIL MAY CONTAIN HARMFUL IMPURITIES. INGESTION MAY
RESULT IN NAUSEA, VOMITING, AND/OR DIARRHEA.
| SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
SUBSTANCE:
CHEMICAL NAME CAS NUMBER WEIGHT - %
PETROLEUM DISTILLATES, HYDRO TREATED LIGHT 64742-47-8 100
PRODUCTS CONTAINING MINERAL OIL WITH LESS THAN
3% DMSO EXTRACT AS MEASURED BY IP 346
| SECTION 4. FIRST-AID MEASURES | |
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE. MOVE OUT OF DANGEROUS AREA.
4.1 INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN AND CONTINUE
TO MONITOR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. GET MEDICAL ATTENTION. CALL A POISON CENTER OR PHYSICIAN.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT, OR WAISTBAND.
4.2 SKIN CONTACT:
WASH SKIN WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. WASH CONTAMINATED
CLOTHING BEFORE USE.
4.3 EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR SEVERAL MINUTES. REMOVE
CONTACT LENSES AFTER ONE TO TWO MINUTES AND CONTINUE FLUSHING FOR SEVERAL
MORE MINUTES. IF REDNESS, ITCHING OR BURNING SENSATION DEVELOPS, SEEK
MEDICAL ATTENTION.
4.4 INGESTION:
ASPIRATION HAZARD IF SWALLOWED. MATERIAL CAN ENTER LUNGS AND CAUSE DAMAGE.
IF ANY OF THE FOLLOWING DELAYED SIGNS AND SYMPTOMS APPEAR WITHIN THE NEXT
6 HOURS, TRANSPORT TO THE NEAREST MEDICAL FACILITY:
FEVER GREATER THAN 101 DEG. F (38.3 DEG. C), SHORTNESS OF BREATH, CHEST
CONGESTION OR CONTINUED COUGHING OR WHEEZING. GIVE NOTHING BY MOUTH. GET
MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. DO NOT
INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
GENTLY WIPE OR RINSE THE INSIDE OF THE MOUTH WITH WATER. IF VOMITING
OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE
LUNGS. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL
ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING
SUCH AS A COLLAR, TIE, BELT, OR WAISTBAND.
4.5 MOST IMPORTANT ACUTE AND DELAYED SYMPTOMS/EFFECTS:
ASPIRATION:
IF MATERIAL ENTERS LUNGS, SIGNS AND SYMPTOMS MAY INCLUDE COUGHING,
CHOKING, WHEEZING, DIFFICULTY IN BREATHING, CHEST CONGESTION, SHORTNESS
OF BREATH, AND/OR FEVER GREATER THAN 101 DEG. F (38.3 DEG. C). THE ONSET
OF RESPIRATORY SYMPTOMS MAY BE DELAYED FOR SEVERAL HOURS AFTER EXPOSURE.
EYE CONTACT:
EXCESSIVE EXPOSURE MAY CAUSE TEMPORARY REDNESS AND MILD IRRITATION TO
EYES.
SKIN CONTACT: MAY CAUSE REDNESS, DEFATING AND CRACKING OF SKIN.
INGESTION:
MAY CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
INHALATION:
MAY CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
AND DIZZINESS, NAUSEA OR VOMITING, HEADACHE, DROWSINESS/FATIGUE,
DIZZINESS/VERTIGO, UNCONSCIOUSNESS.
CHRONIC HEALTH EFFECTS: CHRONIC EXPOSURE MAY CAUSE RESPIRATORY IRRITATION.
RELEVANT ROUTES OF EXPOSURE: EYE, SKIN, INHALATION.
4.6 INDICATION OF IMMEDIATE MEDICAL ATTENTION AND NOTES FOR PHYSICIANS:
PERSONS WITH PRE-EXISTING SKIN, EYE, OR RESPIRATORY CONDITIONS MAY BE AT
AN INCREASED RISK FROM THE IRRITANT PROPERTIES OF THIS MATERIAL. ATTENDING
PHYSICIAN SHOULD TREAT EXPOSED PATIENTS SYMPTOMATICALLY. ASPIRATION DURING
SWALLOWING OR VOMITING MAY SEVERELY DAMAGE THE LUNGS. IF EVACUATION OF
STOMACH CONTENTS IS NECESSARY, USE METHOD LEAST LIKELY TO CAUSE
ASPIRATION.
PROTECTION OF FIRST AIDERS:
NO ACTION SHOULD BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
| SECTION 5. FIRE-FIGHTING MEASURES | |
5.1 FLAMMABLE PROPERTIES:
FLASH POINT: 122 DEG. C / 252 DEG. F (COC)
LOWER EXPLOSION LIMIT: NOT AVAILABLE
UPPER EXPLOSION LIMIT: NOT AVAILABLE
THERMAL DECOMPOSITION:
WHEN HEATED, HAZARDOUS GASES MAY BE RELEASED INCLUDING SULFUR COMPOUNDS.
FIRE AND EXPLOSION HAZARD:
MATERIAL WILL BUM. NOT A FIRE OR EXPLOSION HAZARD.
5.2 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
COMBUSTIBLE MATERIAL. USE CO2, DRY CHEMICAL, OR FOAM. WATER CAN BE USED
TO COOL AND PROTECT PRODUCT.
UNSUITABLE EXTINGUISHING MEDIA:
FORCEFUL APPLICATION OF FIRE EXTINGUISHING AGENTS OR WATER SPRAY MAY
SPREAD BURNING MATERIAL.
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WHEN HEATED, HAZARDOUS GASES MAY BE RELEASED INCLUDING:
SULFUR DIOXIDE. A SOLID STREAM OF WATER WILL SPREAD THE BURNING MATERIAL.
MATERIAL CREATES A SPECIAL HAZARD BECAUSE IT FLOATS ON WATER. THIS
MATERIAL IS HARMFUL TO AQUATIC LIFE.
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION, WHICH MAY BE TOXIC AND/OR
IRRITATING.
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIOUS FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PERSONNEL AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. DO
NOT PPLY DIRECT WATER STREAM. USE FINE WATER SPRAY OR FOAM. COOL
SURROUNDINGS WITH WATER TO LOCALIZE FIRE ZONE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED. WEAR POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS (SCBA) AND PROTECTIVE FIREFIGHTING
CLOTHING (INCLUDES FIREFIGHTING HELMET, COAT, TROUSERS, BOOTS, AND
GLOVES) TO PROTECT AGAINST OTHER BURNING MATERIAL. IF PROTECTIVE
EQUIPMENT IS NOT AVAILABLE OR NOT USED, FIGHT FIRE FROM A PROTECTED
LOCATION OR SAFE DISTANCE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIOUS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID BREATHING MISTS. AVOID SKIN AND
EYE CONTACT. EVACUATE PERSONNEL TO SAFE AREAS. SPILLED MATERIAL MAY CAUSE
A SLIPPING HAZARD. USE APPROPRIATE SAFETY EQUIPMENT. SEE SECTION 8 FOR
INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
6.2 ENVIRONMENTAL PRECAUTIONS AND PROTECTIVE PROCEDURES:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS, SEWERS, WATERWAYS, AND/OR GROUNDWATER. IN THE EVENT OF A
SPILL OR ACCIDENTAL RELEASE, NOTIFY RELEVANT AUTHORITIES IN ACCORDANCE
WITH ALL APPLICABLE REGULATIONS.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLED MATERIAL IF POSSIBLE. ELIMINATE ALL IGNITION SOURCES
INCLUDING SMOKING, FLARES, SPARKS OR FLAMES IN IMMEDIATE AREA. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. COLLECT IN
SUITABLE AND PROPERLY LABELED CONTAINERS. SEE SECTION 13, DISPOSAL
CONSIDERATIONS, FOR ADDITIONAL INFORMATION.
| SECTION 7. HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING PROCESS MISTS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
USE WITH ADEQUATE VENTILATION. MATERIAL CAN ACCUMULATE STATIC CHARGES
WHICH MAY CAUSE AN ELECTRICAL SPARK (IGNITION SOURCE). WHEN THE MATERIAL
IS HANDLED IN BULK, AN ELECTRICAL SPARK COULD IGNITE ANY FLAMMABLE VAPORS
FROM LIQUIDS OR RESIDUES THAT MAY BE PRESENT (E.G., DURING SWITCH-LOADING
OPERATIONS). USE PROPER BONDING AND/OR GROUND PROCEDURES. HOWEVER, BONDING
AND GROUNDS MAY NOT ELIMINATE THE HAZARD FROM STATIC ACCUMULATION. CONSULT
LOCAL APPLICABLE STANDARDS FOR GUIDANCE. DO NOT EAT, DRINK AND/OR SMOKE IN
WORK AREAS. WASH HANDS AFTER USE. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS.
7.2 CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES):
STORE IN COOL PLACE. KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND
WELL-VENTILATED PLACE. STORE IN ACCORDANCE WITH GOOD MANUFACTURING
PRACTICES. STORAGE CONTAINERS SHOULD BE GROUNDED AND BONDED. FIXED
STORAGE CONTAINERS, TRANSFER CONTAINERS AND ASSOCIATED EQUIPMENT SHOULD
BE GROUNDED AND BONDED TO PREVENT ACCUMULATION OF STATIC CHARGE. ODOROUS
AND TOXIC FUMES MAY FORM FROM THE DECOMPOSITION OF THIS PRODUCT IF STORED
AT TEMPERATURES IN EXCESS OF 113 DEG. F (45 DEG. C) FOR EXTENDED PERIODS
OF TIME OR IF HEAT SOURCES IN EXCESS OF 250 DEG. F (121 DEG. C) ARE USED.
STORE AWAY FROM INCOMPATIBLE MATERIALS. SEE SECTION 10 FOR INCOMPATIBLE
MATERIALS.
| SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
CONSULT WITH A HEALTH AND SAFETY PROFESSIONAL FOR SPECIFIC SELECTIONS.
8.1 CONTROL PARAMETER: OCCUPATIONAL EXPOSURE LIMITS
ACGIH TLV (ABSORBED THROUGH SKIN.) TWA:
200 MG/M3, (AS TOTAL HYDROCARBON VAPOR) 8 HOURS.
NIOSH 100 MG/M3 TWA 10 HOUR(S)
OSHA PEL: 100 PPM
OIL MIST, MINERAL:
ACGIH TWA [MIST.]: 5 MG/M3
ACGIH STEL [MIST]: 10 MG/M3
8.2 APPROPRIATE ENGINEERING CONTROLS:
USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE
CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
8.3 PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: USE SAFETY GLASSES WITH SIDE SHIELDS.
BODY PROTECTION: NO SPECIAL CLOTHING IS REQUIRED. SEE HAND PROTECTION.
HAND PROTECTION:
CONTACT SHOULD BE MINIMIZED. USE BUTYL RUBBER, NITRILE, OR NEOPRENE
GLOVES. USE GOOD INDUSTRIAL HYGIENE PRACTICES. IN CASE OF SKIN CONTACT,
WASH HANDS AND ARMS WITH SOAP AND WATER. USE CAUTION WHEN OPENING COVERS
OF STORAGE AND TRANSPORTATION CONTAINERS. 3-NITROANILINE CRYSTALS MAY BE
PRESENT ON THE INTERIOR SURFACE OF THESE OPENINGS. 3-NITROANILINE IS TOXIC
BY DERMAL EXPOSURE.
RESPIRATORY PROTECTION:
CONCENTRATION IN AIR DETERMINES THE LEVEL OF RESPIRATORY PROTECTION
NEEDED. WHEN AIRBORNE CONCENTRATIONS EXCEED THE EXPOSURE LIMIT, USE ONLY
NIOSH CERTIFIED RESPIRATORY EQUIPMENT. POSITIVE-PRESSURE SUPPLIED AIR
RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT CONCENTRATIONS.
OTHER:
REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. FOR NON-FIRE
EMERGENCIES, RESPIRATORY PROTECTION MAY BE NECESSARY AND WEAR APPROPRIATE
PROTECTIVE CLOTHING TO AVOID CONTACT WITH MATERIAL. HAVE EYEWASH STATION
IN WORK AREA. DO NOT CONSUME OR STORE FOOD IN THE WORK AREA. WASH HANDS
BEFORE SMOKING OR EATING. CONCENTRATION OF H2S IN TANLC HEADSPACES MAY
REACH HAZARDOUS VALUES, ESPECIALLY IN CASE OF PROLONGED STORAGE. THIS
SITUATION IS ESPECIALLY RELEVANT FOR THOSE OPERATIONS WHICH INVOLVE DIRECT
EXPOSURE TO THE VAPORS IN THE TANK.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BRIGHT AND CLEAR
ODOR: CHARACTERISTIC OF PETROLEUM
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT / RANGE: NO DATA AVAILABLE
FLASH POINT (COC): 122 DEG. C / 252 DEG. F
EVAPORATION RATE: NO DATA AVAILABLE
UPPER EXPLOSIVE LIMITS (% AIR): NO DATA AVAILABLE
LOWER EXPLOSIVE LIMITS (% AIR): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
VAPOR PRESSURE: <1 MM Hg
VAPOR DENSITY (AIR=1): > 1
RELATIVE DENSITY: 0.85
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
SOLUBILITY IN WATER: NEGLIGIBLE, 0-1 %
PARTITION COEFFICIENT, N-OCTANOLLWATER: > 4
VISCOSITY @ 40 DEG. C: NO DATA
VISCOSITY @ 100 DEG. C: NO DATA
| SECTION 10. STABILITY AND REACTIVITY | |
10.1 CHEMICAL STABILITY:
STABLE UNDER NORMAL TEMPERATURE CONDITIONS AND RECOMMENDED USE.
10.2 POSSIBILITY OF HAZARDOUS REACTIONS:
NO HAZARDOUS REACTIONS IF STORED AND HANDLED AS PRESCRIBED.
10.3 CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES.
10.4 INCOMPATIBLE MATERIALS: STRONG OXIDIZERS
10.5 HAZARDONS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND THE
PRESENCE OF OTHER MATERIALS. SMOKE, CARBON MONOXIDE, SULFUR OXIDES,
HYDROGEN SULFIDE, ALDEHYDES, AND OTHER PETROLEUM DECOMPOSITION PRODUCTS
IN THE CASE OF INCOMPLETE COMBUSTION. PROCESSING MAY RELEASE FUMES AND
OTHER DECOMPOSITION PRODUCTS. FUMES CAN BE IRRITATING.
10.6 HAZARDOUS POLYMERIZATION: WILL NOT POLYMERIZE.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
INHALATION, INGESTION, SKIN AND EYE CONTACT, CENTRAL NERVOUS SYSTEM.
11.2 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (SIMILAR MATERIAL):
ORAL LD50: > 5,000 MG/KG - RAT
INHALATION 4 H LC50: > 5.2 MG/L - RAT
DERMAL LD50: > 2,000 MG/KG - RABBIT
SKIN CORROSION/IRRITATION:
CAUSES MILD SKIN IRRITATION (RABBIT)
CLASSIFICATION: NOT CLASSIFIED AS IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
SLIGHT OR NO EYE IRRITATION (RABBIT)
CLASSIFICATION: NOT CLASSIFIED AS IRRITANT
INHALATION:
MAY CAUSE MILD RESPIRATORY TRACT IRRITATION
CLASSIFICATION: NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS, MOUSE
CLASSIFICATION: DOES NOT CAUSE RESPIRATORY SENSITIZATION
SKIN SENSITIZATION:
DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS, GUINEA PIG
CLASSIFICATION: DOES NOT CAUSE SKIN SENSITIZATION
INGESTION:
MAY CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
REPEATED DOSE TOXICITY:
INHALATION RAT: NO TOXICOLOGICALLY SIGNIFICANT EFFECTS WERE FOUND.
MUTAGENICITY:
TESTS ON BACTERIAL OR MAMMALIAN CELL CULTURES DID NOT SHOW MUTAGENIC
EFFECTS
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SPECIFIC TARGET ORGAN TOXICITY (STOT):
STOT-SINGLE EXPOSURE:
CLASSIFICATION: NOT CLASSIFIED
STOT -REPEATED EXPOSURE:
CLASSIFICATION: NOT CLASSIFIED
ASPIRATION HAZARD:
RISK OF CHEMICAL PNEUMONIA AFTER ASPIRATION. MAY BE FATAL IF SWALLOWED
AND ENTERS AIRWAYS. (BASED ON PHYSICAL DATA.)
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. MAY CAUSE HEADACHES AND DIZZINESS,
IS AN ANESTHETIC AND MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS.
FURTHER INFORMATION:
PROLONGED AND/OR REPEATED SKIN CONTACT WITH LOW VISCOSITY MATERIALS MAY
DEFAT THE SKIN RESULTING IN POSSIBLE IRRITATION AND DERMATITIS
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
EYE CONTACT: PAIN OR IRRITATION, WATERING, REDNESS
INHALATION:
NAUSEA OR VOMITING, HEADACHE, DROWSINESS/FATIGUE DIZZINESS/VERTIGO,
UNCONSCIOUSNESS
SKIN CONTACT: IRRITATION, REDNESS, DEFATTING OF SKIN
11.3 CARCINOGENICITY:
NOT CONSIDERED A CARCINOGEN BY IARC, NTP, OSHA, ACGIH.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOX DATA:
TEST VALUE SPECIES SOURCE
LC50 45MG/L 96H PIMEPHALES PROMELAS IUCLID
LC50 2.2MG/L 96H LEPOMIS MACROCHIRUS EPA
LC50 2.4MG/L 96H ONCORHYNCHUS MYKISS EPA
12.1 MOBILITY:
PARTLY EVAPORATES FROM WATER OR SOIL SURFACES, BUT A SIGNIFICANT
PROPORTION WILL REMAIN AFTER ONE DAY. IF PRODUCT ENTERS SOIL, ONE
OR MORE CONSTITUENTS WILL BE MOBILE AND MAY CONTAMINATE GROUNDWATER.
FLOATS ON WATER. LARGE VOLUMES MAY PENETRATE SOIL AND COULD
CONTAMINATE GROUNDWATER
12.2 AQUATIC AND TERRESTRIAL ECOTOXICITY: TOXIC LONG-TERM
12.3 PERSISTENCE AND DEGRADABILITY: READILY DEGRADABLE
12.4 BIOACCUMULATIVE POTENTIAL:
LOW BIOACCUMULATION EXPECTED. CONTAINS CONSTITUENTS WITH THE POTENTIAL
TO BIO ACCUMULATE.
12.5 OTHER ADVERSE EFFECTS:
FILMS FORMED ON WATER MAY AFFECT OXYGEN TRANSFER AND DAMAGE ORGANISMS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
13.1 DISPOSAL METHODS:
UNCONTAMINATED DISCARDED PRODUCT IS NOT A HAZARDOUS WASTE UNDER RCRA. DO
NOT DUMP INTO ANY SEWERS, ON THE GROUND OR INTO ANY BODY OF WATER. ALL
DISPOSAL PRACTICES MUST COMPLY WITH ALL FEDERAL, STATE, AND LOCAL LAWS
AND REGULATIONS. OFFER SURPLUS AND NON-RECYCLABLE MATERIAL TO A LICENSED
DISPOSAL COMPANY. CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE
FOR DISPOSAL.
13.2 CONTAINER DISPOSAL:
EMPTY CONTAINER RETAINS PRODUCT RESIDUE. OBSERVE ALL HAZARD PRECAUTIONS.
DO NOT DISTRIBUTE, MAKE AVAILABLE, FURNISH OR REUSE EMPTY CONTAINER EXCEPT
FOR STORAGE AND SHIPMENT OF ORIGINAL PRODUCT. REMOVE ALL PRODUCT RESIDUE.
PUNCTURE OR OTHERWISE DESTROY EMPTY CONTAINER AND DISPOSE OF IN A FACILITY
PERMITTED FOR NONHAZARDOUS WASTE.
| SECTION 14. TRANSPORT INFORMATION | |
14.1 UN NUMBER: NOT REGULATED
14.2 UN PROPER SHIPPING NAME: NOT REGULATED
14.3 TRANSPORT HAZARD CLASS: NOT REGULATED
14.4 PACLDNG GROUP (IF APPLICABLE): NOT REGULATED
14.5 MARINE POLLUTANT (YES/NO): NO
14.6 SPECIAL PRECAUTION: NO INFORMATION AVAILABLE
| SECTION 15. REGULATORY INFORMATION | |
U.S. REGULATIONS:
15.1 USA TSCA: LISTED ON THE TSCA INVENTORY.
15.2 SARA SECTION 311/312 HAZARD CATEGORIES:
ACUTE HAZARD: YES
CHRONIC HAZARD: YES
FIRE HAZARD: NO
REACTIVE HAZARD: NO
SUDDEN PRESSURE RELEASE: NO
15.3 CERCLA HAZARDONS SUBSTANCE SARA SECTION 304 RELEASE REPORTING:
COMPONENT(S) REPORTABLE QUANTITY
NONE
15.4 SARA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
COMPONENT(S)/CAS NUMBER CONCENTRATION MIN MAX
NONE
15.5 SARA SECTION 313 TOXIC CHEMICALS:
COMPONENT(S)/CAS NUMBER REPORTING THRESHOLD MIN - CONCENTRATION - MAX
NONE
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST BE
REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
15.6 CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS NOT KNOWN TO CONTAIN CHEMICAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE HARM.
15.7 PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT:
HAZARDOUS SUBSTANCES: NONE
15.8 NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW ACT:
HAZARDOUS SUBSTANCES: NONE
15.9 INTERNATIONAL REGULATIONS:
CANADIAN REGULATIONS:
WHMIS STATEMENT:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS. THIS PRODUCT
IS CLASSIFIED AS NOT CONTROLLED IN ACCORDANCE WITH THE CANADIAN CONTROLLED
PRODUCTS REGULATIONS.
THIS PRODUCT COMPLIES WITH ROHS (RESTRICTION ON HAZARDOUS SUBSTANCES).
OTHER REQUIREMENTS:
INVENTORY LISTING:
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT LISTED
SECTION 8(B) INVENTORY
DSL - CANADIAN DOMESTIC SUBSTANCES LIST LISTED
NDSL - NON-DOMESTIC SUBSTANCES LIST NOT LISTED
EINECS - EUROPEAN INVENTORY OF EXISTING CHEMICAL LISTED
SUBSTANCES/EUROPEAN
ELINCS - LIST OF NOTIFIED CHEMICAL SUBSTANCES NOT LISTED
ENCS - JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES LISTED
IECSC - CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES LISTED
KECL - KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES LISTED
PICCS - PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL LISTED
SUBSTANCES
AICS AUSTRALIA - AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES LISTED
| SECTION 16. OTHER INFORMATION | |
16.1 NFPA AND HMIS HAZARD RATINGS:
NFPA AND HMIS RATINGS HAVE BEEN ASSIGNED TO THIS PRODUCT BASED ON THE
HAZARDS OF ITS INGREDIENT(S). BECAUSE THE USER IS MOST AWARE OF THE
APPLICATION OF THE PRODUCT, THE USER MUST ENSURE THAT THE PROPER PERSONAL
PROTECTIVE EQUIPMENT (PPE) IS PROVIDED CONSISTENT WITH INFORMATION
CONTAINED IN THE PRODUCT SDS. THIS INFORMATION IS INTENDED SOLELY FOR THE
USE OF INDIVIDUALS TRAINED IN THE PARTICULAR HAZARD RATING SYSTEM.
KEY:
0 = LEAST
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) - CLASSIFICATION:
HEALTH 1 SLIGHT
FLAMMABILITY 1 SLIGHT
INSTABILITY OR REACTIVITY 0 MINIMAL
HMIS(R*) [HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (PAINT &
COATING)] - CLASSIFICATION:
HEALTH 1 SLIGHT
FLARMNABILITY 1 SLIGHT
REACTIVITY 0 MINIMAL
NFPA, HMIS(R*) RATING INVOLVES DATA INTERPRETATIONS THAT MAY VARY FROM
COMPANY TO COMPANY. THEY ARE INTENDED ONLY FOR RAPID, GENERAL
IDENTIFICATION OF THE MAGNITUDE OF THE SPECIFIC HAZARD. TO DEAL
ADEQUATELY WITH THE SAFE HANDLING OF THIS MATERIAL, ALL THE INFORMATION
CONTAINED IN THIS SDS MUST BE CONSIDERED. THIS INFORMATION IS SUPPLIED
SOLELY FOR THE USE OF INDIVIDUALS TRAINED IN THE PARTICULAR HAZARD
RATING SYSTEM.
16.2 REVISION INFORMATION:
DATE OF THIS REVISION: 10/27/2015 (VERSION 1.0)
REVISION SUMMARY: GHS/OSHA COMPLIANT SDS
16.3 TRAINING ADVICE:
FOR PROFESSIONAL USE, ONLY AS DIRECTED. PROVIDE ADEQUATE INFORMATION,
INSTRUCTION AND TRAINING FOR OPERATORS. ADDITIONAL REFERENCES STATIC
CHARGES INCLUDE AMERICAN PETROLEUM INSTITUTE 2003 (PROTECTION AGAINST
IGNITIONS ARISING OUT OF STATIC, LIGHTNING AND STRAY CURRENTS) OR
NATIONAL FIRE PROTECTION AGENCY 77 (RECOMMENDED PRACTICE ON STATIC
ELECTRICITY) OR CENELEC CLC/TR 50404 (ELECTROSTATICS - CODE OF PRACTICE
FOR THE AVOIDANCE OF HAZARDS DUE TO STATIC ELECTRICITY).
16.4 KEY OR LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA
SHEET:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
LC50: MEDIAN LETHAL CONCENTRATION
LD50: MEDIAN LETHAL DOSE
NOAEL: NO OBSERVED ADVERSE EFFECT LEVEL
NOEC: NO OBSERVED EFFECT CONCENTRATION
NOEL: NO OBSERVED EFFECT LEVEL
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OPPTS: OFFICE OF PREVENTION, PESTICIDES, AND TOXIC SUBSTANCES
OEL: OCCUPATIONAL EXPOSURE LIMIT
PEL: PERMISSIBLE EXPOSURE LIMIT
PPM: PARTS PER MILLION
STEL: SHORT TERM EXPOSURE LIMIT
TLV: THRESHOLD LIMIT VALUE
TWA: TIME WEIGHTED AVERAGE
ACTION LEVEL:
AN EXPOSURE VALUE SET BY OSHA THAT IS LOWER THAN THE PEL THAT WILL
TRIGGER THE NEED FOR ACTIVITIES SUCH AS EXPOSURE MONITORING AND
MEDICAL SURVEILLANCE.
DECLARE TO READER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION, AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL, AND RELEASE AND IS NOT TO
BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.