| Common Name: | GRANITE SURFACE PLATE CLEANER |
| Manufacturer: | ACCURATE MANUFACTURED PRODUCTS |
| SDS Revision Date: | 5/25/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 44XK14, 44XK15, 44XK16, 44XK17, 44XK18, 44XK19 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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AMPG
ACCURATE MANUFACTURED PRODUCTS GROUP
ISO 9001:2008 CERTIFIED COMPANY
VISIT US ONLINE AND SEARCH OUR CATALOG AT AMPG.COM.
8090 WOODLAND DRIVE
INDIANAPOLIS, IN 46278
P: 317.472.9000
F: 317.472.9010
SAFETY DATA SHEET
THIS SAFETY DATA SHEET CONTAINS ENVIRONMENTAL, HEALTH AND TOXICOLOGY
INFORMATION FOR YOUR EMPLOYEES. PLEASE MAKE SURE THIS INFORMATION IS GIVEN
TO THEM. IT ALSO CONTAINS INFORMATION TO HELP YOU MEET COMMUNITY RIGHT TO
KNOW EMERGENCY RESPONSE REPORTING REQUIREMETNS UNDER SARA TITLE III AND
MANY OTHER LAWS. IF YOU RESELL THIS PRODUCT, THIS SDS MUST BE GIVEN TO THE
BUYER OR THE INFORMATION INCORPORATED IN YOUR SDS.
| SECTION 1: IDENTIFICATION |  |
PRODUCT IDENTIFIER: GRANITE SURFACE PLATE CLEANER
PART NUMBERS: Z9412, Z9410, Z9409, Z9408, Z9407 AND Z9406
COMPANY NAME:
AMPG
8090 WOODLAND DRIVE
INDIANAPOLIS, IN 46278
EMERGENCY CONTACT NUMBER: (317) 472-9000
USES: CLEANING, DEGREASING AND CARE OF GRANITE SURFACES
| SECTION 2: HAZARD IDENTIFICATION | |
PHYSICAL HAZARD CLASSIFICATION: FLAMMABLE LIQUID, CATEGORY 4
SIGNAL WORD: WARNING
PHYSICAL HAZARD PRECAUTIONARY STATEMENTS:
COMBUSTIBLE LIQUID.
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES.
NO SMOKING
KEEP COOL.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IN CASE OF FIRE: CONTACT AUTHORITIES, AVOID BREATHING FUMES AND SMOKE
USE APPROPRIATE MEDIA TO EXTINGUISH.
STORE IN A WELL - VENTILATED PLACE.
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGULATIONS.
HEALTH HAZARD CLASSIFICATION(S):
ACUTE TOXICITY-ORAL-LEVEL 4: WARNING
ACUTE TOXICITY-INHALATION-LEVEL 4: WARNING
SKIN CORROSION/IRRITATION-LEVEL 3: WARNING
EYE DAMAGE/IRRATATION - LEVEL 2A: WARNING
EXCLAMATION MARK
HEALTH HAZARD STATEMENTS:
COMBUSTIBLE LIQUID.
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
KEEP COOL.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IN CASE OF FIRE: CONTACT AUTHORITIES, AVOID BREATHING FUMES AND SMOKE
USE APPROPRIATE MEDIA TO EXTINGUISH.
STORE IN A WELL-VENTILATED PLACE.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL REGULATIONS.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
CAS# % RANGE PEL TLV
ETHANOL, 2-BUTOXY 111-76-2 1% 5% 25 PPM 25 PPM
PROPYLENE GLYCOL 34590-94-8 1% 5% 100 PPM SKIN 100 PPM SKIN
METHYL ETHER
SODIUM TRIPOLY 7758-29-4 1% 5% NOT ESTABLISHED NOT ESTABLISHED
PHOSPHATE
ETHYLENE DIAMINE 64-02-8 1% 5% NOT ESTABLISHED NOT ESTABLISHED
TETRAACETATE
INERT MATERIAL 7732-18-5 70% 90% NOT ESTABLISHED NOT ESTABLISHED
SODIUM METASILICATE 6834-92-0 1% 5% 15 MG/M3 10 MG/M3
SPECIFIC CHEMICAL IDENTITY AND EXACT PERCENTAGES ARE WITHHELD AS TRADE
SECRET.
| SECTION 4: FIRST-AID MEASURES | |
AVOID BREATHING DUST / FUME / GAS / MIST / VAPOURS / SPRAY.
WASH HANDS AND EXPOSED AREAS THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL VENTILATED AREA.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF SKIN IRRITAION OCCURS: GET MEDICAL ADVICE / ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGUALATIONS.
GENERAL:
THIS MATERIAL IS AN ASPIRATION HAZARD AND DEFATS THE SKIN. BREATHING VAPORS
OF HIGH CONCENTRATIONS MAY CAUSE CNS DEPRESSION
EYE CONTACT: SLIGHTLY IRRITATING BUT DOES NOT INJURE EYE TISSUE.
SKIN CONTACT:
LOW ORDER OF TOXICITY. FREQUENT OR PROLONGED CONTACT MAY CAUSE DERMATITIS.
SKIN CONTACT MAY AGGRAVATE AND EXISTING DERMATITIS CONDITION.
INHALATION:
HIGH VAPOR/AEROSOL CONCENTRATIONS (GREATER THAT APPROXIMATELY 100 PPM) ARE
IRRITATING TO THE EYES AND THE RESPIRATORY TRACT, MAY CAUSE HEADACHES,
DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, AND OTHER CENTRAL
NERVOUS SYSTEM EFFECTS, INCLUDING DEATH.
INGESTION:
SMALL AMOUNTS OF THIS PRODUCT ASPIRATED INTO THE RESPIRATORY SYSTEM DURING
INGESTION OR VOMITTING MAY CAUSE MILD TO SEVERE PULMONARY INJURY POSSIBLY
MINIMAL TOXICITY.
FIRST AID:
EYE CONTACT:
FLUSH EYES WITH LARGE AMOUNTS OF WATER UNTIL IRRITATION SUBSIDES. IF
IRRITATION PERSISTS, GET MEDICAL ATTENTION.
SKIN CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER; USE SOAP IF AVAILABLE. REMOVE GROSSLY
CONTAMINATED CLOTHING, INDLUDING SHOES, AND LAUNDER BEFORE REUSE.
INHALATION:
USING PROPER RESPIRATORY PROTECTION, IMMEDIATELY REMOVE THE AFFECTED VICTIM
FROM EXPOSURE. ADMINISTER ARTIFICIAL RESPIRATION IF BREATHING IS STOPPED.
KEEP AT REST. CALL FOR PROMPT MEDICAL ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. KEEP AT REST. GET PROMPT MEDICAL
ATTENTION.
PRECAUTIONS:
SPECIAL PRECAUTIONS:
HEALTH STUDIES HAVE SHOWN THAT MANY HYDROCARBONS POSE POTENTIAL HUMAN
HEALTH RISKS WHICH MAY VARY FROM PERSON TO PERSON. AS A PRECAUTION,
EXPOSURE TO LIQUIDS, VAPORS, MISTS OR FUMES SHOULD BE MINIMIZED.
PERSONAL PROTECTION:
FOR OPEN SYSTEMS WHERE CONTACT IS LIKELY, WEAR SAFETY GLASSES WITH SIDE
SHIELDS, LONG SLEEVES, AND CHEMICAL RESISTANT GLOVES. WHERE CONCENTRATIONS
IN AIR MAY EXCEED THE LIMITS, WORK PRACTICE OR OTHER MEANS OF EXPOSURE
REDUCTION ARE NOT ADEQUATE, NIOSH/MSHA APPROVED RESPIRATORS MAY BE
NECESSARY TO PREVENT OVEREXPOSURE BY INHALATION.
VENTILATION:
THE USE OF MECHANICAL DILUTION VENTILATION IS RECOMMENDED WHENEVER THIS
PRODUCT IS USED IN A CONFINED SPACE, IS HEATED ABOVE AMBIENT TEMPERATURES,
OR IS AGITATE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
AVOID BREATHING DUST / FUME / GAS / MIST / VAPOURS / SPRAY.
WASH HANDS AND EXPOSED AREAS THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IF SWALLOWED: CALL A POISON CENTER /DOCTOR IF YOU FEEL UNWELL.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A POISON CENTER / DOCTOR IF YOU FEEL UNWELL.
IF SKIN IRRITAION OCCURS: GET MEDICAL ADVICE / ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGUALATIONS.
GENERAL HAZARD:
COMBUSTIBLE LIQUID, CAN FORM COMBUSTIBLE MIXTURES AT TEMPERATURES AT OR
ABOVE THE FLASH POINT. STATIC DISCHARGE, MATERIAL CAN ACCUMULATE STATIC
CHARGE WHICH CAN CAUSE AN INCENDIARY ELECTRICAL DISCHARGE. "EMPTY"
CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID AND /OR VAPOR) AND CAN BE
DANGEROUS. DO NOT CUT, WELD, BRAZE, SOLDER, DRILL OR EXPOSE SUCH CONTAINERS
TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
FIRE FIGHTING:
USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT PERSONNEL.
ISOLATE "FUEL" SUPPLY FROM FIRE. USE FOAM, DRY CHEMICAL, OR WATER SPRAY TO
EXTINGUISH FIRE. AVOID SPRAYING WATER DIRECTLY INTO STORAGE CONTAINERS DUE
TO DANGER OF BOIL OVER. THIS LIQUID IS VOLATILE AND GIVES OFF INVISIBLE
VAPORS. EITHER THE LIQUID OR VAPOR MAY SETTLE IN LOW AREAS OR TRAVEL SOME
DISTANCE ALONG THE GROUND OR SURFACE TO IGNITION SOURCES WHERE THEY MAY
IGNITE OR EXPLODE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
LAND SPILL:
ELIMINATE SOURCES OF IGNITION. PREVENT ADDITIONAL DISCHARGE OF MATERIAL,
IF POSSIBLE TO DO SO WITHOUT HAZAR. FOR SMALL SPILLS IMPLEMENT CLEANUP
PROCEDURES; FOR LARGE SPILLS IMPLEMENT CLEANUP PROCEDURES AND, IF IN PUBLIC
AREA, KEEP PUBLIC AWAY AN DADVISE AUTHORITIES. ALSO, IF THIS PRODUCT IS
SUBJECT TO CERCLA REPORTING NOTIFY THE NATIONAL RESPONSE CENTER. PREVENT
LIQUID FROM ENTERING SEWERS, WATERCOURSES OR LOW AREAS. CONTAIN SPILLED
LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS
SAWDUST. RECOVER BY PUMPING OR WITH A SUITABLE ABSORBENT. CONSULT AN EXPERT
ON DISPOSAL REGULATIONS.
WATER SPILL:
ELIMINATE SOURCES OF IGNITION. WARN OCCUPANTS AND SHIPPING IN SUROUNDING
AND DOWNWIND AREAS OF FIRE AND EXPLOSION HAZARD AND REQUEST ALL TO STAY
CLEAR. REMOVE FROM SURFACE BY SKIMMING OR WITH SUITABLE ABSORBENTS. IF
ALLOWED BY LOCAL AUTHORITIES AND ENVIRONMENTAL AGENCIES, SINKING AND / OR
DISPERSANTS MAY BE USED IN NON-CONFINED WATERS. CONSULT AN EXPERT ON
DISPOSAL OF RECOVERED MATERIAL AND ENSURE CONFORMITY TO LOCAL DISPOSAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
AVOID BREATHING DUST / FUME / GAS / MIST / VAPOURS / SPRAY.
WASH HANDS AND EXPOSED AREAS THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL VENTILATED AREA.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IF SWALLOWED: CALL A POISON CENTER /DOCTOR IF YOU FEEL UNWELL.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A POISON CENTER / DOCTOR IF YOU FEEL UNWELL.
IF SKIN IRRITAION OCCURS: GET MEDICAL ADVICE / ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGULATIONS.
VENTILATION REQUIREMENT: USE ADEQUATE LEVEL EXHAUST VENTILATION.
NOTE:
WHERE CARBON MONOXIDE MAY BE GENERATED, SPECIAL VENTILATION MAY BE
REQUIRED. LOCAL EXHAUSE RECOMMENDED WHEN APPROPRIATE TO CONTROL EMPLOYEE
EXPOSURE.
RESPIRATORY PROTECTION:
BASED ON CONTAMINATION LEVEL AND WORKING LIMITS OF THE RESPIRATOR, USE A
RESPIRATOR APPROVED BY NIOSH/MSHA.
EYES: FACE SHIELD AND GOGGLES OR CHEMICAL GOGGLES SHOULD BE WORN.
GLOVES:
IMPERVIOUS GLOVES SHOULD BE WORN. GLOVES CONTAMINATED WITH THE PRODUCT
SHOULD BE DISCARDED. POLYFLUORINATED POLYETHYLENE HAS BEEN SUGGESTED.
OTHER CLOTHING EQUIPMENT:
STANDARD WORK CLOTHING. STANDARD WORK SHOES; DISCARD IF SHOES CAN NOT BE
DECONTAMINATED. STORE CONTAMINATD CLOTHING IN WELL VENTILATED CABINETS OR
CLOSED CONTAINERS. WASH CONTAMINATED CLOTHING AND DRY BEFORE REUSE.
RESPIRATORY PROTECTION:
IN SITUATIONS WHERE VAPOR CONCENTRATIONS EXCEED THE RECOMMENDED EXPOSURE
LIMITS, A NIOSH APPROVED ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLYING
RESPIRATOR SHOULD BE WORN.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
AVOID BREATHING DUST / FUME / GAS / MIST / VAPOURS / SPRAY.
WASH HANDS AND EXPOSED AREAS THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL VENTILATED AREA.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IF SWALLOWED: CALL A POISON CENTER /DOCTOR IF YOU FEEL UNWELL.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A POISON CENTER / DOCTOR IF YOU FEEL UNWELL.
IF SKIN IRRITAION OCCURS: GET MEDICAL ADVICE / ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGUALATIONS.
VENTILATION REQUIREMENT: USE ADEQUATE LEVEL EXHAUST VENTILATION.
NOTE:
WHERE CARBON MONOXIDE MAY BE GENERATED, SPECIAL VENTILATION MAY BE
REQUIRED. LOCAL EXHAUST RECOMMENDED WHEN APPROPRIATE TO CONTROL EMPLOYEE
EXPOSURE.
RESPIRATORY PROTECTION:
BASED ON CONTAMINATION LEVEL AND WORKING LIMITS OF THE RESPIRATOR, USE A
RESPIRATOR APPROVED BY NIOSH/MSHA.
EYES: FACE SHIELD AND GOGGLES OR CHEMICAL GOGGLES SHOULD BE WORN.
GLOVES:
IMPERVIOUS GLOVES SHOULD BE WORN. GLOVES CONTAMINATED WITH THE PRODUCT
SHOULD BE DISCARDED. POLYFLUORINATED POLYETHYLENE HAS BEEN
OTHER CLOTHING EQUIPMENT:
STANDARD WORK CLOTHING. STANDARD WORK SHOES; DISCARD IF SHOES CAN NOT BE
DECONTAMINATED. STORE CONTAMINATD CLOTHING IN WELL VENTILATED CABINETS OR
CLOSED CONTAINERS. WASH CONTAMINATED CLOTHING AND DRY BEFORE REUSE.
RESPIRATORY PROTECTION:
IN SITUATIONS WHERE VAPOR CONCENTRATIONS EXCEED THE RECOMMENDED EXPOSURE
LIMITS, A NIOSH APPROVED ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLYING
RESPIRATOR SHOULD BE WORN.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
FLASH POINT (CCP): 170 DEG. F TCC
BOILING POINT FOR PRODUCT: >212 DEG. F
VAPOR PRESSURE FOR PRODUCT: 20 MMHG
VAPOR DENSITY FOR PRODUCT: >1
SPECIFIC GRAVITY: 1.04
V.O.C.: 8.7% BY VOLUME
WATER SOLUBILITY: SOLUBLE
APPEARANCE: CLEAR THIN LIQUID
PH: 12.8 +/- 0.5
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: TEMPERATURES ABOVE 130 DEG. F
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS: NONE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ETHANOL, 2-BUTOXY 111-76-2:
ACUTE ORAL TOXICITY:
LD 50 GUINEA PIG: 1,200 MG/KG
ACUTE INHALATION TOXICITY:
LC 50 GUINEA PIG: >633 PPM, 1H
ACUTE DERMAL TOXICITY:
LD 50 GUINEA PIG: 2,000 MG/KG
PROPYLENE GLYCOL METHYL ETHER 34590-94-8:
ACUTE ORAL TOXICITY:
LD 50 RAT: 5200 MG/KG
ACUTE DERMAL TOXICITY:
LD 75 RABBIT: 5900 MG/KG
EFFECTS OF ACUTE EXPOSURE:
SKIN CONTACT: LITTLE TO NO EFFECT
SKIN ABSORBTION: YES, NO TXICE EFFECTS UNLIKELY BY THIS ROUTE
EYE CONTACT: SLIGHTLY IRRITATING, WILL NOT DAMAGE EYES
INHALATION:
VAPOR CONCENTRATIONS ABOVE 100 PPM MAY IRRITAT RESPIRATORY TRACT; LOW VAPOR
PRESSURE MAKES DEVELOPMENT OF SUCH A CONCENTRATION UNLIKELY IN AN INDUSTIAL
SETTING
INGESTION:
MAY CAUSE STOMACH DISCOMFORT; MAY CAUSE DIARRHEA; A MASSIVE DOES (100ML)
WOULD BE REQUIRED TO PRODUCT ANY SYMPTOMS IN A HUMAN OF AVERAGE WEIGHT
EFFECTS OF CHRONIC EXPOSURE:
GENERAL:
PROLONGED DELIBERATE EXPOSURE MAY CUASE SKIN CRACKING AND DERMATITIS
SENSITISING: NOT A SENSITIZER
REPRODUCTIVE EFFECT: NO KNOWN EFFECT ON HUMANS OR ANIMALS
SYNERGISTIC WITH: NOT KNOWN
SODIUM TRIPOLY PHOSPHATE 7758-29-4:
ACUTE ORAL TOXICITY:
LD 50 MOUSE: 3100 MG/KG
OTHER TOXIC EFFECTS ON HUMANS:
HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT), OF INGESTION, OF INHALATION.
SLIGHTLY HAZARDOUS IN CASE OF SKIN CONTACT (SENSITIZER, PERMEATOR).
ETHYLENE DIAMINE TETRA ACETATE ACID 64-02-8:
ACUTE ORAL TOXICITY:
LD 50 RAT: 3030 MG/KG
ACUTE DERMAL TOXICITY:
LD 50 RABBIT: >5000 MG/KG
SODIUM METASILICATE 6834-92-0:
THE HAZARD OF SODIUM METASILICATES, BY ALL ROUTES, COMES FROM ITS
CORROSIVITY CAUSED BY THE HIGH ALCALINITY.
ACUTE ORAL TOXICITY:
LD 50 RAT: 600 - 1350 MG/KG
INHALATION: IRRITATING TO THE RESPIRATORY SYSTEM
EYE: CORROSIVE. MAY CAUSE SERIOUS DAMAGE TO EYE, UNLESS TREATED IMMEDIATELY
SKIN: CORROSIVE
| SECTION 12: ECOLOGICAL INFORMATION | |
ETHANOL, 2-BUTOXY 111-76-2:
AQUATIC TOXICITY LC50 FISH: 1490 MG/L
AQUATIC TOXICITY ED50 CRUSTACEA: 550-1000 MG/L
PROPYLENE GLYCOL METHYL ETHER 34590-94-8:
THIS PRODUCT CANNOT ACCUMULATE IN LIVING TISSUE; THIS PRODUCT IS READILY
AND RAPIDLY BIODEGRAEABLE IN THE PRESENCE OF OXYGEN
ETHYLENE DIAMINE TETRA ACETATE ACID 64-02-8:
MATERIAL IS PRACTICALLY NON-TOXIC TO FISH.
ACUTE LC50 (FLATHEAD MINNOW): >100 MG/L
ACUTE LC50 (BLUEGILL): 1030 MG/L
SODIUM METASILICATE 6834-92-0:
GENERAL CONSIDERATION:
SOLUBLE SILICATES UPON DILUTION RAPIDLY DEPOLYMERISE INTO MOLECULAR
SPECIES INDISTINGUISHABLE FROM NATURAL DISSOLVED SILICA.
THEY COMBINE WITH IONS LIKE Ca, Mg, Fe, Al AND OTEHRS TO END UP AS
INSOLUBLE COMPOUNDS SIMILAR TO CONSTITUENTS FO NATURAL SOILS.
HOWEVER, THE PH OF MOST UNDILUTED SILICATE SOLUTIONS IS ABOVE ACCEPTABLE
LIMITS FOR DIRECT DISCHARGE INTO WATERBODIES.
MOBILITY: NOT MOBILE
BIODEGRADABILITY: NOT APPLICABLE ON INORGANIC SUBSTANCES
ACCUMULATION: NO
ECOTOXICITY DATA:
LC50 FISH:
3185 MG PRODUCT/LITRE (BY ANALOGY WITH SODIUMSILICATE WITH MR 3.36, 35%)
EC50 BACTERIA:
>1000 MG PRODUCT/LITRE (BY ANALOGY WITH SODIUMSILICATE WITH MR 3.36, 35%)
EC50 DAPHNIA:
4857 MG PRODUCT/LITRE (BY ANALOGY WITH SODIUMSILICATE WITH MR 3.2, 35%)
IF APPLICABLE, IARL, NPT AND OSHA CARCINOGENS AND CHEMICAL SUBJECT TO THE
REPORTING REQUIREMENTS OF SARA TITLE III, SECTION 313 ARE IDENTIFIED IN
SECTION III WITH AN "*". ADDITIONAL ECOLOGICAL INFORMATION IS NOT
DETERMINED.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
AVOID BREATHING DUST / FUME / GAS / MIST/ VAPOURS / SPRAY.
WASH HANDS AND EXPOSED AREAS THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL VENTILATED AREA.
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
IF SWALLOWED: CALL A POISON CENTER /DOCTOR IF YOU FEEL UNWELL.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A POISON CENTER / DOCTOR IF YOU FEEL UNWELL.
IF SKIN IRRITAION OCCURS: GET MEDICAL ADVICE / ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGUALATIONS.
WASTE DISPOSAL METHOD:
CONSULT LOCAL AUTHORITIES FOR PROPER WASTE DISPOSAL PROCEDURES. EMPTY
DE-PRESSURIZED CONTAINERS CAN NOT BE REUSED. CONSULT FEDERAL, STATE, AND
LOCAL AUTHORITIES FOR APPROVED PROCEDURES.
| SECTION 14: TRANSPORTATION INFORMATION | |
DOT PROPER SHIPPING NAME: (NOT REGULATED)
| SECTION 15: REGULATORY INFORMATION | |
CAS# PEL TLV
ETHANOL, 2-BUTOXY 111-76-2 25 PPM 25 PPM
PROPYLENE GLYCOL METHYL 34590-94-8 100 PPM SKIN 100 PPM SKIN
ETHER
SODIUM TRIPOLY PHOSPHATE 7758-29-4 NOT ESTABLISHED NOT ESTABLISHED
ETHYLENE DIAMINE TETRA 64-02-8 NOT ESTABLISHED NOT ESTABLISHED
ACETATE
INERT MATERIAL 7732-18-5 NOT ESTABLISHED NOT ESTABLISHED
SODIUM METASILICATE 6834-92-0 15 MG/M3 10 MG/M3
| SECTION 16: OTHER INFORMATION | |
IF APPLICABLE, IARL, NPT AND OSHA CARCINOGENS AND CHEMICAL SUBJECT TO THE
REPORTING REQUIREMENTS OF SARA TITLE III, SECTION 313 ARE IDENTIFIED IN
SECTION III WITH AN "*".
NO TESTING IS REQUIRED TO CERTIFY COMPLIANCE WITH THE ABOVE MENTIONED
REGULATION. THE INFORMATION ABOVE IS BASED ON THE DATE OF WHICH WE ARE
AWARE AND IS BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. SINCE THE
INFOMRAITON CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR
CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR AND SINCE DATA MADE AVAOLABLE
SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE DO NOT ASSUME ANY RESPONSIBILITY FOR THE RESULTS OF ITS USE. THIS
INFORMATION IS FURNISHED UPON CONDITION THAT THE PERSON RECEIVING IT SHALL
MAKE HIS OWN DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS
PARTICULAR PURPOSE.
SDS PREPARATION DATE: 5/25/2016
EMERGENCY TELEPHONE: (317) 472-9000